Spatial variations in daily average CO2 concentrations above wetland surface of Xianghai National Nature Reserve, China

Horizontal and vertical variations of daily average CO2 concentration above the wetland surface were studied in Xianghai National Nature Reserve of China in August, 2000. The primary purpose was to study spatial distribution characteristics of CO2 concentration on the four levels of height(0.1 m, 0.6 m, 1.2 m and 2 m) and compare the differences of CO2 concentration under different land covers. Results showed that daily average CO2 concentration above wetland surface in Xianghai National Natural Reserve was lower than that above other wetlands in northeast China as well as the worldwide average, suggesting that Xianghai wetland absorbed CO2 in August and acted as“sink” of CO2. The horizontal variations on the four levels of height along the latitude were distinct, and had the changing tendency of“decreasing after increasing” with the increase of height. The areas with obvious variations were consistent on different levels of height,and those with the highest variations appeared above surface of shore, sloping field, Typha wetland and Phragmites wetland; the vertical variations were greatly different, with the higher variations in Phragmites wetland and Typha wetland, and the lands near the shore and the sloping field with the lower variations. Spatial variations of daily average CO2 concentrations above wet!and surface were affected by surface qualities and land covers.     

锌镉还原法的海水硝酸盐浓度

按照《海洋调查规范》(1991)中锌镉还原法 ,用三对基体来配制NO3 -标准溶液 :NaCl水 (31gNaCl加纯水至 1L)与无氮东海海水ECS、《海洋调查规范》(1991)人工海水SAS(NaCl水加MgSO4)与ECS和Strick land Parsons(1972 )人工海水SP72 (SAS加NaHCO3 )与ECS。经测定 ,且忽略标准曲线方程的截距 ,纯水与ECS的NO3 -还原率比为 0 .2 6 6 ,NaCl水与ECS的比为 0 .70 6 ,SAS与ECS的比为 0 .90 1,而SP72与ECS的比则为1.0 0 9。显然 ,用ECS和等价的SP72定出的值最接近天然海水中NO3 -的浓度。由《海洋调查规范》(1991)SAS定出的浓度须乘上 0 .90 1～ 0 .95 6后才接近海水中NO3 -浓度。     

Acid resistance of methanogenic bacteria in a two-stage anaerobic process treating high concentration methanol Wastewater

In this study, the two-stage upflow anaerobic sludge blanket (UASB) system and batch experiments were employed to evaluate the performance of anaerobic digestion for the treatment of high concentration methanol wastewater. The acid resistance of granular sludge and methanogenic bacteria and their metabolizing activity were investigated. The results show that the pH of the first UASB changed from 4.9 to 5.8 and 5.5 to 6.2 for the second reactor. Apparently, these were not the advisable pH levels that common methanogenic bacteria could accept. The methanogenic bacteria of the system, viz. Methanosarcina barkeri, had some acid resistance and could still degrade methanol at pH 5.0. If the methanogenic bacteria were trained further, their acid resistance would be improved somewhat. Granular sludge of the system could protect the methanogenic bacteria within its body against the impact of the acidic environment and make them degrade methanol at pH 4.5. The performance of granular sludge was attributed to its structure, bacteria species, and the distribution of bacterium inside the granule. Translated from Acta Scientiae Circumstantiae, 2004, 24(4): 633–636 [译自: 环境科学学报]     

11种有机磷农药对海洋微藻致毒效应的研究

通过研究不同盐度条件下１１种有机磷农药对扁藻的相对增长率和叶绿素ａ含量的影响，得到了Ｓ＝３０和Ｓ＝２０时的半数有效浓度，并比较其大小。盐度作为环境因子，影响到有机磷农药的毒性。研究发现，遥有机磷农药在低浓度时出现一定限度的促生长作用；容易进攻细胞膜的有机磷农药对扁藻的致毒性相对较强；此外，有机磷农药的毒性大小与其结构密切相关含有苯环结构的有机磷农药毒性大小不含有苯 有机磷农药的毒性。     

活性污泥法的多变量最优控制Ⅰ.基础理论与DO浓度对运行费用的影响

在现有的关于活性污泥法最优控制研究的基础上，首次提出了以两个最重要的控制参数污泥排放量和溶解氧浓度（ＤＯ）为控制变量、以出水水质为约束条件、以运行费用为性能指标的活性污泥法多变量最优控制的研究问题，并着重进行了基础研究．首先建立了最优控制所必要的基本状态方程与性能指标的泛函表达式．然后通过计算研究了在满足同一出水质量前提下控制不同的ＤＯ浓度时所需要的运行费用．结果表明，ＤＯ为０９ｍｇ／Ｌ时所需运行费用最少，这与主张应当维持ＤＯ浓度大于２ｍｇ／Ｌ的传统观点相比相差甚远；衰减速率常数Ｋｄ不受ＤＯ影响的假设也不合理．     

SBBR同步硝化反硝化处理生活污水的影响因素

序批式生物膜反应器SBBR采用塑料鲍尔环填料,在有氧情况下用于处理实际生活污水.该反应器能很好地创造缺氧微环境,载体生物膜具有吸附储碳能力,出现了良好的同步硝化和反硝化现象.反应器中溶解氧浓度在较大的范围内(0.8～4.0 mg·L-1)能有效地实现同步硝化和反硝化.当溶解氧浓度大于4.0 mg·L-1后,TN容积去除率大幅下降,出水TN大幅上升.增加载体生物膜厚度有利于同步硝化和反硝化.进水浓度基本不影响脱氮的效率,但出水TN随进水浓度增加而升高,建议原水浓度高时可增加后续脱氮处理或减少进水量来满足出水要求.优化运行方法和参数后,SBBR连续运行的TN去除率可稳定在74%～82%.     

复介电常数在水土污染监测中的应用研究

采用短路同轴线法测量了淀粉聚乙烯醇共混体样品,在含水率、离子浓度不同时的复介电常数,研究了频率、离子浓度、含水率与相对复介电常数的关系。结果表明,淀粉PVA复介电常数的实部对含水率很敏感,虚部在500~700MHz频段随含盐量升高呈对数增加,这为利用测量相对复介电常数进行水土系统离子污染监测,提供了可能和实验依据。     

五种重金属离子对黑褐新糠虾的急性毒性试验

通过Cu、Hg、Cd、Zn、Pb等5种重金属离子对黑褐新糠虾的急性毒性试验,分别得出了5种重金属离子对黑褐新糠虾的24、48、72、96 h半致死浓度及安全浓度,依次为:Cu2 0.625、0.161、0.161、0.125、0.013 mg/L;Zn2 4.028、1.083、0.917、0.583、0.058mg/L;Cd2 2.679、0.625、0.250、0.161、0.016mg/L;Pd2 13.750、13.750、9.583、1.917、0.192mg/L;Hg2 0.161、0.150、0.150、0.150、0.015 mg/L。研究结果表明:黑褐新糠虾对5种金属离子的敏感性为Cu2 >Hg2 >Cd2 >Zn2 >Pb2 ,黑褐新糠虾作为水域重金属离子的监测生物具有较明显的优势。     

ACCU采样和PIXE技术用于PM10污染溯源的研究

使用美国RP公司生产的多通道自动采样系统(ACCU)在上海吴淞工业区进行冬季3个月8个不同风向的PM10采样；使用质子激发X荧光发射方法(PIXE)测定颗粒物中18个无机元素浓度．结果发现，8个风向的质量浓度分布取决于不同方位的大气质量状况．将大气颗粒物中的元素浓度作为环境污染指纹，8个方位的无机元素浓度分布与采样点周围的居民住宅、道路交通和工矿企业的排放密切相关，表明该方法能准确地确定排放源的范围和污染来源．研究结果表明，ACCU采样系统和PIXE分析技术的优化组合可为大气污染溯源、治理和改善环境空气质量提供一种快速和准确可靠的新方法．     

几种不同浓缩技术回收水中病毒的效果

实验表明,即使病毒剂量低到一个感染性病毒也可使人感染,并可在人群间造成传播。因此,水环境的病毒污染深为人们关切。 水中的致病性病毒主要来自人和动物的排泄物及医院废水。目前已从各种水体中检测出120多种危及人类健康的肠道病毒和其它病毒。 世界卫生组织要求,用最灵敏的方法试验,在100—1000L饮用水中应不含病毒。因此,病毒的浓缩技术是监测水中病毒的前提。 现在国内外使用的浓缩技术方法很多,但都不甚理想。我们用几种不同的方法回收自来水和污水厂出水中实验性污染的病毒,以便选择具有快速、简便、适用性广泛、浓缩水样体积大和回收病毒效率高的技术。